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Q.

(A) : NaCl in water and organic acids in benzene show abnormal molecular mass.
(R) : Abnormal molecular mass is obtained when the substance in the solution undergoes either dissociation or association.

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a

Both (A) and (R) are true and (R) is not the correct explanation of (A)
 

b

(A) is true but (R) is false

 

c

Both (A) and (R) are true and (R) is the correct explanation of (A)

 

d

Both (A) and (R) are false
 

answer is A.

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Detailed Solution

 Vant Hoff factor can be defined as:
i = Normal molar massAbnormal molar mass--(1)
NaCl in water dissociates to Na+ and Cl-, thus forming two resultant ions giving out i = 2.
Using (1), Normal molar mass of NaCl = 2 * Abnormal molar mass of NaCl.Therefore, assertion can be concluded to be true.Similarly, acetic acid dimerizes in benzene thus forming an association compound.
Thus, reasoning can also be concluded to be true.
Hence, correct option is: (A)  Both (A) and (R) are true and (R) is the correct explanation of (A)

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