Q.

(A) : The electronic configuration of Cr in the ground state is [Ar]4s13d5 Instead of [Ar]4s23d4
(R) : The average exchange energy associated with 4s13d5 configuration is less when compared to that of 4s23d4

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a

Both ‘A’ and ‘R’ are true and ‘R’ is the correct explanation of ‘A’.

b

‘A’ is true but ‘R’ is false

c

Both 'A' and 'R' are false

d

Both ‘A’ and ‘R’ are true and ‘R’ is not the correct explanation of ‘A’

answer is C.

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Detailed Solution

The electronic configuration of Cr is [Ar]4s13d5(half filled configuration)

This is due to the stability of half filled configuration.

The stability is due to symmetry and exchange energy.

As no. of unpaired electrons(or parallel spin e-s) increases, exchange energy increases and stability increases.

In 4s13d5 ,  no. of unpaired electrons=6

In 4s23d4 ,  no. of unpaired electrons=4

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