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Q.

(A) : The radial probability distribution curves of 1s, 2p, 3d orbitals are identical in shape.
(R) : The number of nodal planes present in these orbitals is different.

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a

Both ‘A’ and ‘R’ are true and ‘R’ is the correct explanation of ‘A’.

b

‘A’ is true but ‘R’ is false

c

Both 'A' and 'R' are false

d

Both ‘A’ and ‘R’ are true and ‘R’ is not the correct explanation of ‘A’

answer is B.

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Detailed Solution

(A) : The radial probability distribution curves of 1s, 2p, 3d orbitals are identical in shape.

Radial nodes =n-l

1s orbital =1-0 =1

2p  orbital =2-1=1

3d orbital =3-2=1

(R) : The number of nodal planes present in these orbitals is different.

l=0 for s -orbital

l=1 for p -orbital

l=2 for d -orbital

so both assertion and reason are true but ‘R’ is not the correct explanation of ‘A’

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