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Q.

(A) : The value of van der Waals constant “a”, is larger for ammonia than for nitrogen.
(R) : Hydrogen bonding is present in ammonia.

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a

Both (A) and (R) are correct and (R) is the correct explanation of (A)

b

Both (A) and (R) are correct but (R) is not the correct explanation of (A)

c

(A) is True but (R) is False

d

Both (A) and (R) are false

answer is A.

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Detailed Solution

  • If the hydrogen bonding takes place at intervals a molecule itself is named unit hydrogen bonding. 
  • It takes place in compounds containing two teams such that one cluster contains an atom connected to a negative atom and therefore the other cluster contains an extremely electronegative atom connected to a lesser electronegative atom of the opposite group.
  • We have to remember that the ammonia contains tough intermolecular forces of attraction. Intermolecular hydrogen bonding is absent in nitrogen. 
  • Hence, the value of Van der Waals constant 'a' is bigger for ammonia than for nitrogen.
  • So, Both (A) and (R) are correct and (R) is the correct explanation of (A).
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