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Q.

(A) : Thermal stability of the hydrides of VIA group elements decreases from H2O to H2Po.
(R) : The heats of dissociation of M – H bond of hydrides of VIA group decreases down the group.
The correct answer is

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a

(A) is true but (R) is false

b

(A) is false but (R) is true

c

Both (A) and (R) are true and (R) is the correct explanation of (A)

d

Both (A) and (R) are true and (R) is not the correct explanation of (A)

answer is A.

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Detailed Solution

Thermal stability1 size of atomsBond dissociation energy

Size of group-16 elements increases down the group, consequently the bond dissociation energy (or heat of dissociation) between M-H bond decreases and hence, the thermal stability decreases.

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