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Q.

(A) : TlCl₃acts as a good oxidant
(R) : Tl⁺³ is less stable than Tl⁺

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a

A and R are true, R explains A

b

A and R are true, R does not explain A

c

A is true, but R is false

d

A is false, but R is true

answer is A.

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Detailed Solution

Tl⁺³ is less stable than Tl⁺due to inert pair effect.

$\underset{(Oxidant)}{{Tl}^{3 +}} + 2 e^{-} \overset{}{\to} {Tl}^{+} (reduction)$

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(A) : TlCl3acts as a good oxidant(R) : Tl+3 is less stable than Tl+