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Q.

(A) : Viscosity of H2SO4 > viscosity of HCl
(R) : Molecules of H2SO4 are involved in H-bonding but not the molecules of HCl

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a

(A) is true but (R) is false

b

Both (A) and (R) are correct and (R) is the correct explanation of (A)

c

Both (A) and (R) are false

d

Both (A) and (R) are correct but (R) is not the correct explanation of (A)

answer is A.

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Detailed Solution

  • Statement (A) is true because H2SO4 has a higher viscosity than HCl at the same temperature and pressure. 
  • Viscosity is the measure of a fluid's resistance to flow, and it is determined by the intermolecular forces between the molecules of the fluid. 
  • The stronger the intermolecular forces, the higher the viscosity.
  • Statement (R) is also true because H2SO4 can form intermolecular hydrogen bonds due to the presence of polar O-H and S=O bonds in its molecule, whereas HCl is a non-polar molecule and does not have the ability to form hydrogen bonds. 
  • Hydrogen bonds are stronger than other intermolecular forces such as London dispersion forces, which are present in both H2SO4 and HCl. 
  • Therefore, the presence of hydrogen bonding in H2SO4 increases its intermolecular forces and makes it more viscous than HCl.
  • So, both (A) and (R) are correct and (R) is the correct explanation of (A).
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