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Q.

A 0.1097 sample of As2O3  required  26.10  mL  ofKMnO4 solution for its titration. The molarity of KMnO4 solution is

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a

0.02

b

0.04

c

0.018

d

0.3

answer is C.

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Detailed Solution

 

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Let  molarity  of  KMnO4  solution  be  M   Eq.  ofAs2O3=Eq.  KMnO4solution          WEAs2O3 = NV1000KMnO40.1097198×4=26.10×M×51000Equivalent  weightAs2O3=1984 ;  Normality of  KMnO4 =M ×5molarity of KMnO4=0.017    0.018

Note:  n-factor = change in oxidation state

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