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Q.

A 0.166 g sample of an organic compound was digested with conc. H2SO4 and then distilled
with NaOH. The ammonia gas evolved was passed through 50.0 mL of 0.5 N H2SO4. The
 acid used for ammonia if neutralised requires 30.0 mL of 0.25 N NaOH for complete neutralization. The mass percentage
of nitrogen in the organic compound is____.

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answer is 63.

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Detailed Solution

Explain Kjeldahl and Duma's method. Derive the expression for percentage of  nitrogen. - Sarthaks eConnect | Largest Online Education Communitymillieq of ammonia = millieq of sulphuric acid used=millieq of NaOH=30x.25=.75 grams of nitrogen = 7.5x14x10-3= 0.105 g  % of nitrogen =0.105x1000.166=63.25%

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