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Q.

A 0.2 M urea solution is isotonic with 100% ionized NaCl solution. Boiling point of NaCl solution is ( assume molality = molarity, Kb of water = 0.52 K.kg.mol-1 )

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a

0.520c

b

0.0520c

c

1.040c

d

0.1040c

answer is B.

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Detailed Solution

For isotonic solutions :

i1C1 = i2C2

1(0.2M) = 2C2 

Molarity of NaCl = 0.1 M

Tb=Kb.m Tb=0.52(0.1) =0.052 K Tb =373.052 K =0.0520 c

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