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Q.

A 1.0g sample of pyrolusite ore containing  MnO2 (MW=87) was dissolved in a concentrated HCl solution and liberated  Cl2(g) was passed through a concentrated KI solution releasing I2  . If the liberated iodine required 16ml of 1.25M sodium thiosulphate (Na2S2O3 ) solution,(Na2S2O3 changes to Na2S4O6), mass percentage of  MnO2  in the given sample is

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a

43.5%

b

87%

c

21.75%

d

0.875%

answer is B.

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Detailed Solution

MnO2 + 4HCl MnCl2 + Cl2 + 2H2O Cl2 + 2KI2KCl + I2 I2 + 2Na2S2O3Na2S4O6 +2NaI Number of moles of Iodine reacted = 12(number of moles of Hypo reacted)

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