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Q.

A 100ml solution of 0.1N HCl was titrated with 0.2N NaOH solution. The titration was discontinued after adding 30ml of NaOH solution. The remaining titration was completed by adding 0.25N KOH solution. The volume of KOH required for completing the titration is

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a

70 ml

b

32 ml

c

16 ml

d

35 ml

answer is C.

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Detailed Solution

Initial volume of HCl taken = 100ml
I:  HCl
  Va = ?
  Na = 0.1N
  NaOH
  Vb = 30ml
  Nb = 0.2N
  VaNa = VbNb
  Va(0.1) = 30(0.2)
  Va = 60 ml
  Volume of 0.1N HCl neutralized by 30 ml of 0.2N NaOH = 60ml
  Volume of 0.1N HCl left over = (100-60)ml = 40ml
II:  HCl
  Va = 40ml
  Na = 0.1N
  KOH
  Vb = ?
  Nb = 0.25N
  VaNa = VbNb
  40(0.1) = Vb(0.2)
  Vb = 16 ml
  Volume of 0.25 KOH required to neutralize 40ml of 0.1N HCl = 16 ml

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