Q.

A 27 % (wt/wt) aqueous ammonia has a specific gravity of 0.90 at 298 K. Correct statements are

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a

The normality of NH4OH solution is 7.5

b

10 mL of the above solution is diluted to a litre. 10 mL of the diluted solution requires 12.5 mL of 0.05 NHCI for complete neutralisation. The strength of this ammonia solution is 0.063 N.

c

The molality of the solution of NH4OH is 10.57

d

The mole fraction of water in the solution is 0.78

answer is A, C, D.

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Detailed Solution

(a) Weight of water in 100 gm solution
= 100-27= 73gm
Molality of NH4OH =1000×2735×73=10.57
(b) 100 gms of solution =1000.90=111.1cm3
Normality- of solution =1000×2735×111.1=6.9
(c) Moles of NH=2717, moles of H2O=10018
Xwater =100/1810018+2717=5.555.55+1.59=0.78
(d) Strength of diluted ammonia solution  =12.5×0.0510=0.063N

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