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Q.

(A) 3o-amines have low boiling points than isomeric 1o and 2o-amines.
(R) 1o and 2o-amines can form intermolecular H-bonding but not 3o-amines.

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a

Both (A) and (R) are true and (R) is the correct explanation of (A)

b

Both (A) and (R) are true but (R) is not the correct explanation of (A)

c

(A) is true but (R) is false

d

Both (A) and (R) are false

answer is A.

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Detailed Solution

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Primary amines ,secondary amines are more polar,and participate in hydrogen bonding.Tertiary amine doesnot invove in hydrogen bonding the boiling point order is primary > secondary > teriary

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