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Q.

A 5.1 wt % solution of H2SO4 has a density 1.03 g cm-3 at 298 K. The mole fraction and molarity of the acid, respectively, are

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a

1.96×102,1.07

b

1.07 and 1.96×102

c

9.78×103 and 5.35×101

d

5.33×101,9.78×103

answer is C.

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Detailed Solution

94.9 gm of water =94.918=5.27 moles 
Moles of H2SO=5.198=0.052
Mole fraction of acid=0.0525.27+0.052=9.78×103
Molarity of the acid=1001.03cm3contain 0.052 moles of H2SO
=1000cm3 contain 1000×0.052×1.03100=0.535.

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