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Q.

(A) Acetic acid does not give a haloform test. 

(R) Acetic acid has no hydrogen.

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a

(A) is true but (R) is false

b

Both (A) and (R) are true but (R) is not the correct explanation of (A)

c

Both (A) and (R) are true and (R) is the correct explanation of (A)

d

Both (A) and (R) are false

answer is C.

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Detailed Solution

Aldehydes and ketones can be tested for the presence of a CH3CO group using haloform.

CH3COR + 3I2+ 4OH-CHI3 + RCOO-+ 3I- + 3H2O

Because acetic acid behaves as an acid in the presence of OH ions and does not create a CHX3 haloform, it does not undergo the haloform reaction. Therefore, the assertion is correct.

Since acetic acid has three alpha hydrogens, the reason is incorrect.

Hence , Option C is correct.

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