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Q.

(a) An aromatic compound ‘A’ (C7H602) on reaction with aqueous Ammonia and heating forms compound ‘B’. ‘B’ on heating with Br2 and alcoholic potash forms compound ‘C’ of molecular formula C6H7N. Write the reactions involved and identify ‘A’ , ‘B’ and ‘C’.

OR

(b) A compound ‘A’ on reduction with Iron scrap and hydrochloric acid gives compound ‘B’ with molecular formula C6H7N. Compound ‘B’ on rection with CHCl3 and alcoholic KOH produces an obnoxious smell of carbylamine due to formation of ‘C’. Identify ‘A’, ‘B’ and ‘C’ and write the chemical reactions involved.

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Detailed Solution

(a)

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OR

(b)

Reduction of nitro compound.
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Carbylamine Reaction 
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Hence ‘A’, ‘B’ and ‘C’ are 
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‘C’ has obnoxious smell.

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(a) An aromatic compound ‘A’ (C7H602) on reaction with aqueous Ammonia and heating forms compound ‘B’. ‘B’ on heating with Br2 and alcoholic potash forms compound ‘C’ of molecular formula C6H7N. Write the reactions involved and identify ‘A’ , ‘B’ and ‘C’.OR(b) A compound ‘A’ on reduction with Iron scrap and hydrochloric acid gives compound ‘B’ with molecular formula C6H7N. Compound ‘B’ on rection with CHCl3 and alcoholic KOH produces an obnoxious smell of carbylamine due to formation of ‘C’. Identify ‘A’, ‘B’ and ‘C’ and write the chemical reactions involved.