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Q.

‘A’ and ‘B’ are two volatile liquids.A mixture of ‘A’ and'B' is prepared.A graph is plotted between vapour pressure of liquid mixture and mole fraction. The following plot is obtained

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From the graphical represent identify the liquid mixture

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a

C6H5NH2+C6H5OH

b

C6H14+C7H16

c

C2H5OH+CS2

d

HNO3+H2O

answer is C.

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Detailed Solution

From the graph it is evident that 

A) ptotal>pA+pB

B) pA>pAoxA

C) pB>pBoxB

The liquid mixture shows positive deviations from Raoult's law.

The H-bonds of C2H5OH are weakened by the addition of CS2

A-B interactions are weaker than A-A and B-B interactions.

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‘A’ and ‘B’ are two volatile liquids.A mixture of ‘A’ and'B' is prepared.A graph is plotted between vapour pressure of liquid mixture and mole fraction. The following plot is obtainedFrom the graphical represent identify the liquid mixture