Q.

‘a’ and ‘b’ are Van der Waals constants. Units of  ba will be

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a

atm . lit-2. mole-1

b

atm . lit-1. mole-1

c

atm . lit. mole-1

d

atm-1 . lit-1. mole

answer is A.

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Detailed Solution

I)p=an2v2;a=pv2n2units  of  'a'  are  atm.lit2.mole2II) v=nbb=vnunits  of  'b'  are  lit.mole1III)   ba=lit.mole1atm.lit2.mole2ba=atm-1.lit-1.mole

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