Q.

(A) Anilinium chloride is more acidic than ammonium chloride.
(R) Anilinium ion is resonance stabilized.

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a

Both (A) and (R) are true but (R) is not the correct explanation of (A)

b

Both (A) and (R) are true and (R) is the correct explanation of (A)

c

Both (A) and (R) are false

d

(A) is true but (R) is false

answer is C.

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Detailed Solution

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Aniline is weaker base than ammonium chloride. In NH4CI or aliphatic amines, the non-bonding electron pair of N is localized and is fully available for coordination with a proton. On the other hand, in aniline or other aromatic amines. The nonbonding electron pair is delocalised into benzene ring by resonance.

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