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Q.

A, B and C are three complexes of chromium(III) with empirical formula  CrCl3O6H12. All the three complexes have water and chloride ion as ligands. Complex A doesnot react with concentrated  H2SO4, where as B and C lose  13.5% and 6.75% of their original mass, respectively,on treatment with concentrated  H2SO4. The compound A,B and C respectively are.

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a

A=[Cr(H2O)6]Cl3;B=[Cr(H2O)4Cl2]Cl.2H2O;C=[Cr(H2O)5Cl]Cl2.H2O

b

A=[Cr(H2O)6]Cl3; B=[Cr(H2O)4Cl2]Cl.2H2O;C=[Cr(H2O)5Cl]Cl2.H2O

c

A=[Cr(H2O)5]Cl3.H2O;B=[Cr(H2O)6]Cl3;C=[Cr(H2O)4Cl2]Cl.H2O

d

A=[Cr(H2O)5Cl]Cl2.H2O;B=[Cr(H2O)4]Cl3;C=[Cr(H2O)6Cl2]

answer is B.

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