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Q.

A big irregular shaped vessel contained water, conductivity of which was 2.56 x 10-3S-1m-1. 585 g of NaCl was then added to the water and conductivity after the addition of NaCl, was found to be 3.06 x 10-3S-1m-1. The molar conductivity of NaCl at this concentration is 1.5 x 10-2S-1m2mol-1. The capacity of vessel if it is fulfilled with water, is

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a

3 x 104 L

b

3 x 105 L

c

3 x 108 L

d

30 L

answer is D.

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Detailed Solution

m=kc1.5×102=3.06×1032.56×103cc=130mol/m3=130×103molL1=585/58.5v
v = 3 x 105 L

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