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Q.

A blue colouration (in solution or precipitate) is not obtained when :

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a

ammonium hydroxide dissolves in copper sulphate

b

cobalt chloride reacts with NH4SCN in presence of amyl alcohol

c

ferric chloride reacts with sodium ferrocyanide

d

aqueous ammonia reacts with white precipitate of silver (I) chloride

answer is D.

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Detailed Solution

Silver(I) chloride is created as a white precipitate when the silver cation (Ag+) and chlorine anion (Cl-) combine in the presence of soluble chlorides such hydrochloric acid. In contrast to acids like HNO3, this precipitate dissolves in aqueous ammonia and forms a complex ion as

AgCl+NH3AgNH32+Cl

Here, blue colouration (in solution or precipitate) is not obtained.

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