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Q.

A body-centered cubic lattice is made up of hollow spheres of B. Spheres of solid A are present in hollow spheres of B. Radius A is half of radius of B. What is the ratio of total volume of spheres of B unoccupied by A in a unit cell and volume of unit cell?

 

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a

73π64

b

73128

c

7.π24

d

7π643

answer is D.

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Detailed Solution

Number of atoms of B in unit cell = 2
Total volume of B unoccupied by A in a unit cell

2×43R3r3×π=7πR33

 Vol. of unit cell =a3=6433R3

 For bcc, 3a=4R

 ρratio =7πR3/36433R3=7π643

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