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Q.

A bromoalkane ‘X’ reacts with magnesium in dry ether to form compound ‘Y’. The reaction of ‘Y’ with methanal followed by hydrolysis yield an alcohol having molecular formula, C4H10O. The compound ‘X’ is

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a

1-bromopropane

b

bromomethane

c

2-bromopropane 

d

bromoethane

answer is C.

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Detailed Solution

Given:

  • X is a bromoalkane.
  • X + Mg/ether → Y (Grignard reagent).
  • Y reacts with methanal, then hydrolysis, gives C4H10O (which is butan-1-ol or butan-2-ol).

For the alcohol C4H10O:

  • If the alcohol is butan-1-ol, you'll need a propyl Grignard (from 1-bromopropane, CH3CH2CH2Br) and methanal.
  • 1-bromopropane + Mg/ether gives propyl magnesium bromide (Y).
  • Propyl magnesium bromide + methanal → butan-1-ol (after hydrolysis).

So, the compound X is 1-bromopropane (CH3CH2CH2Br).

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