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Q.

A carbon compound catains 4.07% hydrogen, 24.27 % carbon and 71.65% chlorine. Its nuclear mass is 98.96 gm. What are its empirical and molecular formulas?

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Detailed Solution

Element% CompositionAtomic RatioSimple Ratio
Carbon24.2724.2712=2.022.022.02=1
Hydrogen4.074.071=4.074.072.02=2
Chlorine71.6571.6535.5=2.022.022.02=1

Emperical formula = CH2Cl
M.F = (E.F)n
n= molecular weight  emperical formula weight 
Emperical formula weight CH2Cl
=12+2+35.5=49.5n=98.9649.5=2
Therefore, Molecular formula
(CH2Cl)2 = C2H4Cl2

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