Q.

A carbon compound contains 12.8% carbon 2.1% Hydrogen 85.1% bromine. The molecular weight of the compound is 187.9 calculate the molecular formula.

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Detailed Solution

Element%Atomic Weight%/At.wtSimple ratio
C12.81212.812=1.0671.0671.067=1
H2.112.11=2.121.067=2
Br85.18085.180=1.0671.0671.067=1

Empirical formula = CH2Br
Empirical formula weight
= 12 + (2 × 1) + 80 = 94
The molecular weight =187.9 (given)
n= molecular weight  empirical formula weight =187.994=2
Molecular formula = (Empirical formula)n
CH2Br2=C2H4Br2

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A carbon compound contains 12.8% carbon 2.1% Hydrogen 85.1% bromine. The molecular weight of the compound is 187.9 calculate the molecular formula.