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Q.

A : Catenation property of phosphorous is more than Nitrogen
R : Bond energy of N – N is less than P - P

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a

(A) is true but (R) is false

b

(A) is false but (R) is true

c

Both (A) & (R) are true (R) is the correct explanation of (A)

d

Both (A) & (R) are true (R) is not the correct explanation of (A)

answer is A.

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Detailed Solution

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The single N--N bond is weaker than the single P--P bond due to high interelectronic repulsion of the non-bonding electrons in N2, owing to small bond length. Therefore, the catenation property is weaker in nitrogen as compared to phosphorus.

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A : Catenation property of phosphorous is more than NitrogenR : Bond energy of N – N is less than P - P