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Q.

A certain hydrate has the formula MgSO4·xH2O. A quantity of 54.2 g of the compound is heated in an oven to drive off the water. If the steam generated exerts a pressure of 24.8 atm in a 2.0 L container at 120°C, calculate x

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a

2

b

7

c

6

d

5

answer is D.

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Detailed Solution

 Applying idea gas equation

pv=nRT

weight =54.2

Molecular weight =120+18x

Pressure =24.8

Volume =2 L

Temperature =393k

24.8×2= given mass  molar mass ×0.0821×393.

24.8×2=x×54.2(120+18x)×0.0821×393.

After solving this equation, we get the value of x= 6.95.

Therefore, option D is correct.

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