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Q.

A certain mixture of HCl and CH3COOH is 0.1M in each of the acids. 20 mL of this solution is titrated against 0.1 M NaOH. By how many unit does the pH change from the start to the stage when the HCl is almost completely neutralized and acetic acid remains unreacted?

Ka for acetic acid =2×105

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a

2

b

1.5

c

3.25

d

3

answer is C.

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Detailed Solution

 meq. of HCl=20×0.1=2; pH=1

Volume of solution on complete neutralization of 

HCl=40ml

 meq. of AcOH=20×0.1=2;

pH=12pKalogcc=240; pH=3

 ΔpH=2

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