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Q.

A certain reaction is exothermic by 220 kJ and does 10 kJ of work. What is the change in the internal energy of the system at constant temperature?

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a

-230 kJ 

b

+230 kJ

c

+210 kJ

d

-210 kJ 

answer is D.

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Detailed Solution

Given: 

q=-220 KJ (heat released)
work done, ω=10kJ, ΔU=? 
as work done by system                 at constant temp.
 By 1st law of Thermodynamics

=q+w=

ΔU=22010=230kJ

ΔH=ΔU+ΔnRT220=ΔU+10

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