Q.

A certain sample of cuprous sulphide is found to have composition Cu1.8S, because of incorporation of cu2+ ions in the lattice. What is the mole % of cu2+ in total copper content in this crystal?

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a

88.88%

b

11.11%`

c

99.8%

d

None of these

answer is B.

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Detailed Solution

Two Cu+ replaced by one Cu2+
Total loss of Cu = 0.2 mole
So, mole of Cu2+ present in Cu1.8S = 0.2
∴ % of Cu 2+ in total copper content
=0.21.8×100=11.11

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