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A chemical reaction cannot occur at all if its :

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$ΔH is (+) ve and ΔS is (-) ve$

$ΔH is (-) ve and ΔS is (+) ve$

$ΔH and ΔS are (+)ve but ΔH < TΔS$

$ΔH and ΔS are (-) ve but ΔH > TΔS$

answer is A.

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Detailed Solution

$∆ G = ∆ H - T ∆ S$

When $∆ H = + ve; and ∆ S = - ve$ ,under these conditions $∆ G = + ve$ and reaction is non -spontaneous in the given direction

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