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Q.

 A chemist opened a cupboard and found four bottles containing water solutions, each of which had lost its label. Bottles 1, 2,3 contained colourless solutions, while bottle 4 contained a blue solution. The labels from the bottles were lying scattered on the floor of the cupboard. They were :
Copper (II) sulphate,                               Hydrochloric acid
Lead nitrate                                             Sodium Carbonate
By mixing samples of the contents of the bottles, in pairs the chemist made the following observations :
Bottle 1 + Bottle 2 White precipitate is formed
Bottle 1 + Bottle  3  White precipitate is formed
Bottle 1 + Bottle  4   White precipitate is formed
Bottle 2 + Bottle  3   Colourless and odourless gas is evolved.
Bottle 2 + Bottle  4   No visible reaction is observed
Bottle 3 + Bottle  4  Blue precipitate is formed

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 A chemist opened a cupboard and found four bottles containing water solutions, each of which had lost its label. Bottles 1, 2,3 contained colourless solutions, while bottle 4 contained a blue solution. The labels from the bottles were lying scattered on the floor of the cupboard. They were :Copper (II) sulphate,                               Hydrochloric acidLead nitrate                                             Sodium CarbonateBy mixing samples of the contents of the bottles, in pairs the chemist made the following observations :Bottle 1 + Bottle 2 →White precipitate is formedBottle 1 + Bottle  3  →White precipitate is formedBottle 1 + Bottle  4  → White precipitate is formedBottle 2 + Bottle  3 →  Colourless and odourless gas is evolved.Bottle 2 + Bottle  4 →  No visible reaction is observedBottle 3 + Bottle  4 → Blue precipitate is formed