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Q.

A cinema hall has equidistant rows 1 m apart. The length of the cinema hall is 287 m and it has 287 rows. From one side of the cinema hall, laughing gas (N2O) is released and from the other side, tear gas (C6H5COCH2Cl) is released. In which rows, spectators will be laughing and weeping simultaneously?

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a

187th row from N2O and 100throw from C6H5COCH2Cl

b

287th row from N2O and 187throw from C6H5COCH2Cl

c

100th row from C6H5COCH2Cl and 287 from N2O

d

100th row from both

answer is A.

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Detailed Solution

Molar weight of  C8H7Ocl=8×12+7×1+16+35.5=154.5g
Molar weight of  N2O=2×14+16=44g
According to Graham’s law of diffusion, 
 rN2OrC8H7OCl=MC8H7OClMN2O=154.544=3.5=1.87:1
 dN2O=1.872.87×287=187th row from N2O side
dC8H7OCl=1.02.87×287=100th  row from weeping gas side
Therefore, the spectator from the side of N2O in the 187th row will be laughing and weeping simultaneously. Alternatively, the spectator from the side of weeping as in the  100th row will be laughing and weeping simultaneously.

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