Q.

(A) cis 3-chloroprop-2-enoic acid is less stable than its trans-form. 

(R) The dipole moment of cis-form is greater than transform

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a

(A) is true but (R) is false

b

Both (A) and (R) are true but (R) is not the correct explanation of (A)

c

Both (A) and (R) are true and (R) is the correct explanation of (A)

d

Both (A) and (R) are false

answer is B.

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Detailed Solution

The assertion is correct since trans-isomers are often more stable for acrylic systems than cis-isomers. The greater unfavorable steric interaction of the substituents in the cis-isomer is to blame for this. Reason also holds true because cis-forms are polar in nature and have a certain value of dipole moment, but trans-forms often have a dipole moment of zero depending on whether the substituents on both sides of a double bond are the same or not.

Hence, Option B is correct

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