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Q.

A coffee cup calorimeter initially contains 125 g of water, at a temperature of 24.2° C, 8 g of ammonium nitrate (NH4NO3), also at 24.2° C, is added to the water, and the final temperature is 18.2° C, what is the heat of solution of ammonium nitrate in kJ/mol? (The specific heat capacity of the solution is 4.2 J/°C.)

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a

37.3 kJ/mol

b

39.5 kJ/mol

c

33.51 kJ/mol

d

32.2 kJ/mol

answer is A.

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Detailed Solution

Moles of given compound 


nNH4NO3=880=0.1ΔH=4.2×(24.218.2)×(125+8)0.1×11000 =33.51kJ/mol

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