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Q.

A colourless water-soluble solid ‘X’ on heating gives equimolar quantities of Y and Z. Y gives white dense fumes with HCl  and Z also gives similar reaction with NH3.  Y gives brown precipitate with Nessler’s reagent and Z gives white precipitate with nitrates of  Ag+,Pb2+ and Hg+.  'X' is :

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a

FeSO4

b

NH4Cl

c

NH4NO3

d

NH4NO2

answer is A.

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Detailed Solution

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NH4ClΔNH3Y+HClZ NH3Y+2K2[HgI4]Nessler's  reagent+3KOH H2NHgO.HgIbrown  ppt.iodide  of  Millon's  base+7KI+H2O

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