Q.

A compound has a cubical arrangement and it consist of atoms of P, Q and R.P atoms are present at the corners, Q atoms occupy face center position and R occupy alternate tetrahederal void as well as all octahedral void. If all the atoms lying on any one body diagonal are missing, then what would be the formula?

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a

PQ4R8

b

PQ3R8

c

P3Q12R20

d

P3Q12R32

answer is B.

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Detailed Solution

p82=6×18=3/4

a6×12=3

R 4+4=811=6

fcc unit cell 3/4:3:6

1:4:8

PQ4R8

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