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Q.

A compound of vanadium has a magnetic moment (μ) of 1.73 BM. If the vanadium ion in the compound is present as V x+, then, the value of x is?

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a

2

b

1

c

3

d

4

answer is D.

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Detailed Solution

 Given μ=n(n+2)=1.73BM
(where n is number of unpaired electrons)
n=1; 23V=1s22s22p63s23p64s23d3

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for n = 1 it must release 4 electrons, first two from 4s-orbital and then next two electrons from 3d-orbital. So, x = 4.

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