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Q.

A compound on analysis was found to contain 53.33%C, 15.5%H, and the rest nitrogen. The formula of the compound is

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a

C3H7N

b

C4H10N

c

C2H8N

d

C2H7N

answer is B.

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Detailed Solution

Total percent composition of the molecule is 100% or the total mass of the molecule is 100 g. Mass of C in the molecule is 53.33 g (53.33%), mass of hydrogen is 15.5 g ( or 15.5%).

Mass of nitrogen is calculated as:

Mass of nitrogen=100 g-(15.5 g+53.33 g) =31.17 g

Number of moles of C is calculated as:

Moles of C=WeightMolar mass =53.33 g12 g/mol =4.44 mol

Mole of H is calculated as:

Mole of H=15.5 g1 g/mol =15.5 mol

Mole of N is calculated as:

Mole of N=31.17 g14 g/mol =2.22 mol

Formula of the compound determine by diving the moles of C, N, and H with 2.22.

Ratio of C:H:N=C4.442.22H15.52.22N2.222.22 =C2H7N

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