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Q.

A compound related to acetylacetone is 1,1,1-trifluoro-acetyl acetone (abbreviated Hffa) CF3COCH2COCH3.It forms complexes in a manner similar to acetylacetone. Both Be2+and Cu2+form complexes with ffa halving formula Mffa2. Regarding these complexes the correct statements is/are

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a

Both the complexes of Be2+ and Cu2+ are coloured

b

Be2+ complex is tetrahedral and can exhibit optical isomerism only

c

Cu2+ complex is square planar and can exhibit geometrical isomerism only

d

Be2+ complex is diamagnetic but Cu2+ complex is paramagnetic

answer is A, B, C.

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Detailed Solution

Be2+ Complex is tetrahedral can exhibit optical isomerism as is do not possess plane of symmetry Cu2+ complex is square planar and it can exhibit geometrical isomerism. Be2+ complex is diamagnetic and colourless where as Cu2+ complex is paramagnetic and coloured since Cu isi in +2 oxidation state with d9 configuration

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Note the dotted line indicates a bond pointing into the plane of paper, and the wedge indicates a bond pointing out of the plane of paper

Geometrical isomers of Cut+a2 are

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