Q.

A compound that gives a positive iodoform test is :

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a

1-pentanol

b

3-pentanone

c

3-pentanol

d

2-pentanone

answer is B.

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Detailed Solution

Alcohols and ketones with a CH3CO (methyl ketone) group are found using the iodoform test.
When a substance containing methyl ketone combines with iodine in the presence of a base, the result is haloform, a precipitate that is yellow in colour.

You may write pentanone as CH3CH2CH2(C=O)HCH3

containing a single methyl ketone group.
As a result, the iodoform test may be positive.

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