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Q.

A compound 'X' is acidic and it is soluble in NaOH solution, but insoluble in NaHCO3 solution. Compound X also gives violet colour with neutral FeCO3 solution. The compound X is

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a

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b

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c

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d

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answer is B.

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Detailed Solution

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Step-by-Step Reasoning

1. Acidic Nature & Solubility

  • Compound X is "acidic" and soluble in NaOH:
    This means X reacts as an acid, forming a salt or getting ionized in strong base.
  • X is insoluble in NaHCO₃:
    Carboxylic acids (like benzoic acid or acetic acid) dissolve in both NaOH and NaHCO₃, but weaker acids (like most phenols) do not dissolve in NaHCO₃. So, X is a weak acid—most likely a phenol.

2. Violet Colour with Neutral FeCl₃

  • Only phenols (and some enols or salicylates) give characteristic violet, blue or green coloration with neutral FeCl₃, due to complex formation.

3. Conclusion

  • Combining these clues:
    • Acidic, but not strong enough to dissolve in NaHCO₃: points to phenol or substituted phenol.
    • Violet colour with FeCl₃: phenol is the textbook example.
  • Thus, Compound X is most probably phenol (C₆H₅OH).

Final Answer: Compound X is phenol (C₆H₅OH).

 

 

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