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Q.

(A) Conc.H2SO4 reacts with KCl to give HCl gas
(R) HCl cannot be oxidised by conc.H2SO4

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a

(A) is true but (R) is false

b

Both (A) and (R) are true and (R) is the correct explanation of (A)

c

Both (A) and (R) are false

d

Both (A) and (R) are true and (R) is not the correct explanation of (A)

answer is A.

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Detailed Solution

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KCl and H2​SO4​ react to give only HCl but not chlorine Cl2​ gas, whereas KI and H2​SO4​ react to liberate iodine (free halogen).
This is because HBr and HI are powerful oxidising agents, and they are also thermodynamically less stable than HCl. Thus easily dissociates to H2​ and X2​ (X=I/Br) at higher temperatures. And, conc. H2​SO4​ is a fairly effective oxidising agent.
The reaction involved is:
2HX+H2​SO4​→SO2​+X2​+2H2​O for X=I/Br
HCl is only a mild reducing agent, and it is not easily oxidised to free chlorine gas by conc.H2​SO4​.

 

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