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Q.

A constant current was flown for one minute through a solution of KI. At the end of experiment, liberated I2 consumed 150ml of 0.01Msolution of Na2S2O3. Average rate of current flow is

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a

9.65A

b

4.825A

c

2.4125A

d

1.206A

answer is C.

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Detailed Solution

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When electricity passed throught the KI solution I2 is llibetated ,The I2 liberated is reacted with Na2S2O3. The reactions taking place are , 

2S2O32-S4 O62-+ 2e-  (n- factor= 22=1)

milli. Eq. of KI= milli. Eq of I2 liberated                              = milli. Eq  of Na2S2O3                             = 150 ×0.01×1(n-factor)                              = 1.5 milli.Eq                             = 1.5 × 10-3  Eq.  since 96500 coulombs = 1 Eq.  1.5 ×10-3 Eq= 96500 ×1.5×10-3 coulombs  Q= it  i=Qt=96500×1.5×10-360 sec on solving  i=2.4125 amp

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