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Q.

A container of fixed volume has a mixture of one mole of hydrogen and one mole of helium in equilibrium at temperature T. Assuming that gases are ideal, the correct statement(s) is (are)

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a

The average energy per mole of the gas mixture is 2RT

b

The ratio of speed of sound in the gas mixture to that in helium gas is6/5

c

The ratio of the rms speed of helium atoms to that of hydrogen molecules is 1/2

d

The ratio of the rms speed of helium atoms to that of hydrogen molecules is 12

answer is A, B, D.

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Detailed Solution

For the mixture equivalent degrees of freedom is calculated using the relation

Feq=n1f1+n2f2n1+n2

feq=5+32=4

U=f2nRT

For mixture, U=42nRT

 Energy per mole: Un=2RT

For mixture, γ=1+2f=1+12=32

Mmix=1×2+1×42=3

γHe=1+23=53

Ratio of speed of sound = γmixMmixMHeγHe=65

Vms=3RTMratio=24=12

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