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Q.

A container of fixed volume has a mixture of one mole of hydrogen and one mole of helium in equilibrium at temperature T. Assuming the gases are ideal, the correct statement(s) is (are)

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a

The ratio of speed of sound in the gas mixture to that in helium gas is 6/5

b

The average energy per mole of the gas mixture is 2RT

c

The ratio of the rms speed of helium atoms to that of hydrogen molecules is 1/2

d

The ratio of the rms speed of helium atoms to that of hydrogen molecules is 12

answer is A, B, D.

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Detailed Solution

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According to question no. of mole of hydrogen = no. of mole of helium =1

Total internal energy, u

=f12nRT+f2dmRTu=32RT+52RT=4RT

Average internal energy per mole =u2n=4RT2=2RT

We know that Vsound=γRTM

n1+n2γmix1=n1γ11+n2γ212γmix1=1531+1751

2γmix1=32+52=4γmix1=12γmix=32

VsmixVsHe=γmixMmix×MHeγHe=32×43×53=65

Mmix=1×2+1×42=3

We know that Vrms=3RTM

  VrmsHeVrmsH2=MH2MHE=24=12

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