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Q.

A container with 100 gram oleum is labeled as 109% by mass. % of SO3 remaining in container is ____?

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a

60

b

35

c

20

d

40

answer is B.

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Detailed Solution

 Oleum is a mixture of H2SO4 and SO3

Let mass of oleum be 100 gram

 Let mass of SO3=x  ''g

 Then mass of H2SO4=(100-x)g

nSO3= Weight of SO3 gram molecular weight of SO3=x80

SO3+H2OH2SO4  nSO3=nH2SO4

 mass of H2SO4 formed =98x80

 mass of H2SO4 already present + mass of H2SO4 formed = Total mass of oleum 

(100-x)+98x80=109

98x80-x=109-100  x=40 g

40% of SO3 is remaining 

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