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Q.

A crystal is made of particles A and B. A forms FCC packing and B occupies all the octahedral voids. If all the particles along the plane as shown in figure are removed, then, the formula of the crystal would be:
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a

A2B

b

A5B7

c

A7B5

d

AB

answer is A.

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Detailed Solution

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Atoms "A" forming FCC packing

Effective atoms of A = 8×18+6×12=4

Octahedral voids = 4 ; Tetrahedral voids = 8

Atoms along diagonal plane is removed, octahedral voids remains same.Only tetrahedral voids are present along diagonal plane

Number of "B" atoms = 4

Formula A4B4 = AB

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